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The reactivity of Bi_n⁻clusters (n= 2 to 30) with O₂is found to display even-odd alternations. The open-shell even-sized Bi_n⁻clusters are more reactive than the closed-shell odd-sized clusters, except Bi₁₈⁻, which exhibits no observable reactivity toward O₂. We have investigated the structure and bonding of Bi₁₈⁻to understand its remarkable resistance to oxidation. We find that the most stable structure of Bi₁₈⁻consists of two Bi₈cages linked by a Bi₂dimer, where each atom is bonded to three neighboring atoms. Chemical bonding analyses reveal that each Bi uses its three 6pelectrons to form three covalent bonds with its neighbors, resulting in a Bi₁₈⁻cluster without any dangling bonds. We find that the robust Bi₁₈framework along with the totally delocalized unpaired electron is responsible for the surprising inertness of Bi₁₈⁻toward O₂. The Bi₁₈framework is similar to that in Hittorf’s phosphorus, suggesting the possibility to create bismuth nanoclusters with interesting structures and properties. 

Abstract This article presents a comprehensive study that focuses on the techno-economic analysis of co-located wind and hydrogen energy integration within an integrated energy system (IES). The research investigates four distinct cases, each exploring various configurations of wind farms, electrolyzers, batteries, hydrogen storage tanks, and fuel cells. To obtain optimal results, the study employs a sophisticated mathematical optimization model formulated as a mixed-integer linear program. This model helps determine the most suitable component sizes and hourly energy scheduling patterns. The research utilizes historical meteorological data and wholesale market prices from diverse regions as inputs, enhancing the study’s applicability and relevance across different geographical locations. Moreover, sensitivity analyses are conducted to assess the impact of hydrogen prices, regional wind profiles, and potential future fluctuations in component prices. These analyses provide valuable insights into the robustness and flexibility of the proposed IES configurations under varying market conditions and uncertainties. The findings reveal cost-effective system configurations, strategic component selections, and implications of future energy scenarios. Specifically comparing to configurations that only have wind and battery combinations, we find that incorporating an electrolyzer results in a 7% reduction in the total cost of the IES, and utilizing hydrogen as the storage medium for fuel cells leads to a 26% cost reduction. Additionally, the IES with hybrid hydrogen and battery energy storage achieves even higher and stable power output. This research facilitates decision-making, risk mitigation, and optimized investment strategies, fostering sustainable planning for a resilient and environmentally friendly energy future. 

Abstract Green hydrogen produced using renewable electricity could play an important role in a clean energy future. This paper seeks to analyze the techno-economic performance of integrated wind and hydrogen systems under different conditions. A co-located wind and hydrogen hybrid system is optimized to reduce the total system cost. We have adopted and improved a state-of-the-art techno-economic tool REopt, developed by the National Renewable Energy Laboratory (NREL), for optimal planning of the integrate energy system (IES). In addition to wind and electrolyzer components, we have also considered battery energy storage, hydrogen tank, and hydrogen fuel cell in the IES. The results show that (i) adding electrolyzers to the grid-connected wind energy system could reduce the total system cost by approximately 8.9%, and (ii) adding electrolyzers, hydrogen tank, and hydrogen fuel cells could reduce the total system cost by approximately 30%.